An Old Story in New Light: X-Ray Powder Diffraction Provides Novel Insights into a Long-Known Organic Solid-State Rearrangement Reaction
نویسندگان
چکیده
The first in situ diffraction study of the long-known solid-state rearrangement of p-bromobenzeneazotribenzoylmethane is reported. This proof-of-principle study demonstrates how modern laboratory X-ray powder diffraction, accompanied by up-to-date processing tools, can be used to monitor and describe mechanisms of organic solid-state reactions while it also underpins its necessity for structural characterisation of in situ formed crystalline phases. (doi: 10.5562/cca2127)
منابع مشابه
Preparation of Nickel Nanoparticles by Intramolecular Reaction of Nickel(II) Hydrazine Complex in the Solid State at Room Temperature
Ni6(N2H4)6(SO4)4(OH)2(H2O)8](SO4)(H2O)10 complex was prepared according to literature report. The reaction between aforementioned complex via sodium alkoxides as a reactants, were carried out in the solid state. The [Ni6(N2H4)6(SO4)4(OH)2(H2O)8](SO4)(H2O)10 undergoes an intramolecular two electrons oxidation-reduction reaction at room temperature and metallic nickel nanoparticles (Ni1-Ni5) was ...
متن کاملSynthesis and characterization of nanowires Hausmannite (Mn3O4) by solid-state thermal decomposition
In this study, we synthesis one-dimensional (1D) manganese(III) Schiff base coordination polymer [Mn(Brsalophen)(μ1,3-N3)]n by reaction of MnCl2·6H2O and tetradentate Schiff base ligand Brsalophen at the presence of NaN3 in methanol and characterized by elemental analyses (CHN) and FT-IR spectroscopy. It was used as a new precurs...
متن کاملSynthesis and characterization of nanowires Hausmannite (Mn3O4) by solid-state thermal decomposition
In this study, we synthesis one-dimensional (1D) manganese(III) Schiff base coordination polymer [Mn(Brsalophen)(μ1,3-N3)]n by reaction of MnCl2·6H2O and tetradentate Schiff base ligand Brsalophen at the presence of NaN3 in methanol and characterized by elemental analyses (CHN) and FT-IR spectroscopy. It was used as a new precurs...
متن کاملSynthesis of Different Copper Oxide Nano-Structures From Direct Thermal Decomposition of Porous Copper(ΙΙ) Metal-Organic Framework Precursors
Copper oxide nanostructures have been successfully synthesized via one-step solid-state thermolysis of two metal-organic frameworks, [Cu3(btc)2] (1) and [Cu(tpa).(dmf)] (2), (btc = benzene-1,3,5-tricarboxylate, tpa = therephtalic acid = 1,4-benzendicarboxylic acid and dmf = dimethyl formamide) under air atmosphere at 400, 500, and 600°C. It has also been found that the reaction temperature pla...
متن کاملCobalt oxide nanoparticles by solid-state thermal decomposition: Synthesis and characterization
In this study, mononuclear octahedral cobalt(III) Schiff base complex [CoL3], L = (5-bromo-2-hydroxybenzyl-2-furylmethyl)imine, was synthesized from the reaction of Co(NO3)2•6H2O and the Schiff base ligand L in methanol as solvent. It used as a new precursor to prepare spinel type cobalt oxide nanoparticles by a facile solid-state thermal decomposition. Controlling the temperature and time, Co3...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
دوره شماره
صفحات -
تاریخ انتشار 2013